• How Tethers Control the Chemo- and Regio-Selectivities of Intramolecular Cycloadditions between Aryl-1-Aza-2-Azoniaallenes and Alkenes

Hong, X.; Liang, Y.; Brewer, M.; Houk, K.N. Org. Lett. 2014, 16(16), 4260-4263. [Supporting Information]

• Fragmentation of Bicyclic γ-Silyloxy-β-hydroxy-α-diazolactones as an Approach to Ynolides

Bayir, A.; Brewer, M. J. Org. Chem. 2014, 79(13), 6037-6046. [Supporting Information]

• Formal and Total Synthesis of (±)-Cycloclavine

Jabre, N.D.; Watanabe, T.; Brewer, M. Tetrahedron Lett. 2014, 55(1), 197-199. [Supporting Information]

• Intramolecular Polar [4^⊕ + 2]-Cycloadditions of Aryl-1-aza-2-azoniaallene Salts: Unprecedented Reactivity Leading to Polycyclic Protonated Azomethine Imines

Bercovici, D.A.; Ogilvie, J.M.; Tsvetkov, N.; Brewer, M. Angew. Chem., Int. Ed. 2013, 52(50), 13338-133441. [Supporting Information]

• Synthesis of Demissidine by a Ring Fragmentation 1,3-Dipolar Cycloaddition Approach

Zhang, Z.; Giampa, G.M.; Draghici, C.; Huang, Q.; Brewer, M. Org. Lett. 2013, 15(9), 2100-2103 [Supporting Information]

• Stereoelectronic Effects in the Fragmentation of γ-Silyloxy-β-hydroxy-α-diazocarbonyl Compounds

Jabre, N.D.; Brewer, M., J. Org. Chem. 2012, 77(21), 9910-9914 [Supporting Information]

• Stereospecific Intramolecular C–H Amination of 1-Aza-2-azoniaallene Salts

Bercovici, D.A.; Brewer, M. J. Am. Chem. Soc. 2012, 134 (24), 9890-9893 [Supporting Information] 

• Iodine(III)-Mediated Bicyclic Diazenium Salt Formation

Al-Bataineh, N.Q.; Brewer, M. Tetrahedron Lett. 2012, 53 (40), 5411-5413  

• A Ring Fragmentation Approach to Medium-Sized Cyclic 2-Alkynones

Tsvetkov, N.P.; Bayir, A.; Schneider, S.; Brewer, M. Org. Lett. 2012, 14 (1), 264-267 [Supporting Information] 

• Synthetic Approaches to Bicyclic Diazenium Salts

Wyman, J.; Javed, M.I.; Al-Bataineh, N.; Brewer, M. J. Org. Chem. 2010, 75 (23), 8078-8087 [Supporting Information] 

• Preparation of Tethered Aldehyde Ynoates and Ynones by Ring Fragmentation of Cyclic γ-Oxy-β-hydroxy-α-diazo Carbonyls

Published as a Featured Article

Bayir, A.; Draghici, C.; Brewer, M. J. Org. Chem. 2010, 75 (2), 296–302 [Supporting Information] 

• An Efficient Synthetic Approach to Polycyclic 2,5-Dihydropyrroles from α-Silyloxy Ketones

Draghici, C.; Huang, Q.; Brewer, M. J. Org. Chem. 2009, 74 (21), 8410–8413. [Supporting Information]

• Synthesis of Fused and Bridged Bicyclic Diazenium Salts by Intramolecular Cycloaddition

Javed, M.I.; Wyman, J.M.; Brewer, M., Org. Lett. 2009, 11(10), 2189–2192. [Supporting Information]

• Lewis acid promoted carbon-carbon bond cleavage of γ-silyloxy-β-hydroxy-α-diazoesters

Draghici, C.; Brewer, M., J. Am. Chem. Soc. 2008, 130(12), 3766-3767. [Supporting Information]

• Chlorodimethylsulfonium Chloride-Mediated Formation of Phenyl-α-chloroazoalkanes

Wyman, J.M.; Jochum, S.; Brewer, M., Synth. Comm. 2008, 38(21), 3623-3630.

• Diphenyldiazomethane

Javed, M.I., Brewer, M., Organic Syntheses 2008, 85, 189-195.

• Diazo Preparation via Dehydrogenation of Hydrazones with “Activated” DMSO

Javed, M.I., Brewer, M. Org. Lett. 2007, 9, 1789-1792. [Supporting Information]

• Conversion of hydrazones to alkyl chlorides under Swern oxidation conditions

Brewer, M. Tetrahedron Lett. 2006, 47, 7731-7733.